Ikerbasque. Basque Foundation for Science

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Science in Basque Country

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Seventh Framework Programme

2012 Annual Report
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Vadim Soloshonok

Vadim Soloshonok

Ikerbasque Research Professor
(USA)

  • Doctor in Organic Chemistry from the Academy of Sciences of Ukraine (1987, Institute of Bioorganic Chemistry, Kiev, USSR)
  • 20+ year of research and teaching experience in Ukraine, Russia, Poland, Italy, Japan and USA. h index: 45 (January, 2013)
  • Research Line: Organic Chemistry (methodology, asymmetric synthesis, self-disproportionation of enantiomers), Fluorine Chemistry, Chiral Nanotechnology, Astrochemistry
  • Has come from the post of Visiting Professor, Member of the Institute of Chemical Biology and Drug Discovery, Department of Chemistry, State University of New York at Stony Brook, NY, USA
  • Has joined the Department of Organic Chemistry I, University of the Basque Country, UPV/EHU in San Sebastian
    Email: v.soloshonok@ikerbasque.org

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Publications

2013

Aceña, J. L.; Sorochinsky, A. E.; Katagiri, T.; Soloshonok, V. A. (2013)
Unconventional preparation of racemic crystals of isopropyl 3,3,3-trifluoro-2-hydroxypropanoate and their unusual crystallographic structure: the ultimate preference for homochiral intermolecular interactions
Chem. Commun.

Sorochinsky, A. E.; Aceña, J. L.; Soloshonok, V. A. (2013)
Self-Disproportionation of Enantiomers of Chiral, Non-Racemic Fluoroorganic Compounds: Role of Fluorine as Enabling Element
Synthesis

X. Ding, H. Wang, J. Wang, S. Wang, D. Lin, L. Lv, Y. Zhou, X. Luo, H. Jiang, Aceña, J. L.; V. A. Soloshonok, H. Liu. (2013)
Synthesis of polysubstituted ?-amino cyclohexane carboxylic acids via Diels–Alder reaction using Ni(II)-complex stabilized ?-alanine derived dienes
Amino Acids

M. V. Shevchuk, V. P. Kukhar, G.-V. Roeschenthaler, B. S. Bassil, K. Kawada, V. A. Soloshonok, A. E. Sorochinsky (2013)
New Asymmetric Approach to ?-Trifluoromethyl Isoserines
RSC Advances

K. V. Turcheniuk, V. P. Kukhar, G.-V. Roeschenthaler, J. Luis Acena, V. A. Soloshonok, A. E. Sorochinsky (2013)
Recent advances in the synthesis of fluorinated aminophosphonates and aminophosphonic acids
RSC Advances

2012

Röschenthaler, G.-V.; Kukhar, V. P.; Kulik, I. B.; Michael Yu. Belik, M. Y.; Sorochinsky?, A. E.; Rusanov, E. B.; Soloshonok, V. A. (2012)
Asymmetric synthesis of phosphonotrifluoroalanine and its derivatives using N-tert-butanesulfinyl imine derived from fluoral
Tetrahedron Lett.

Hu, X. Y.; Shan Z. X.; Soloshonok, V. A. (2012)
First Experimental Evidence of an Intramolecular H Bond between Aliphatic Cl and Aromatic C-H
Cryst. Growth Des

Shibata, N.; Nishimine, T.; Tokunaga, E.; Kawada, K.; Kagawa, T.; Sorochinsky, A. E.; Soloshonok, V. A. (2012)
Organic base-catalyzed stereodivergent synthesis of (R)- and (S)-3-amino-4,4,4-trifluorobutanoic acids
Chem. Comm.

Nakamura, T.; Tateishi, K.; Tsukagoshi, S.; Hashimoto, S.; Watanabe, S.; Soloshonok, V. A.; Aceña, J. L.; Kitagawa, O. (2012)
Self-Disproportionation of Enantiomers of Non-racemic Chiral Amine Derivatives Through Achiral Chromatography
Tetrahedron

Soloshonok, V. A.; Roussel, C.; Kitagawa, O.; Sorochinsky, A. E. (2012)
Self-Disproportionation of Enantiomers via Achiral Chromatography: a Warning and Extra Dimension in Optical Purifications
Chem. Soc. Rev.

Aceña, J. L.; Sorochinsky, A. E.; Soloshonok, V. A. (2012)
Recent advances in asymmetric synthesis of ?-(trifluoromethyl)-containing ?-amino acids
Synthesis

Turcheniuk, K. V.; Poliashko, K. O.; Kukhar, V. P.;Rozhenko, A. B.; Soloshonok, V. A.; Sorochinsky, A. E. (2012)
Efficient asymmetric synthesis of trifluoromethylated ?-aminophosphonates and their incorporation into dipeptides
Chem. Commun.

Soloshonok, V. A.; Aceña, J. L.; Ueki, H.; Han, J. (2012)
Design and synthesis of quasi-diastereomeric molecules with unchanging central, regenerating axial and switchable helical chirality via cleavage and formation of Ni(II)–O and Ni(II)–N coordination bonds
Beilstein J. Org. Chem

Houck, D.; Aceña, J. L.; Soloshonok, V. A. (2012)
Alkylations of Chiral Nickel(II) Complexes of Glycine under Phase-Transfer Conditions
Helvetica Chimica Acta

2011

Soloshonok, V. A.; Nelson, D. J. (2011)
Alkene selenenylation: A comprehensive analysis of relative reactivities, stereochemistry and asymmetric induction, and their comparisons with sulfenylation
Beilstein J. Org. Chem.

Röschenthaler, G.-V.; Kukhar, V. P.; Kulik, I. B.; Sorochinsky, A. E.; Soloshonok, V. A. (2011)
Convenient Synthesis of Fluoroalkyl a- and b-Aminophosphonates
J. Fluor. Chem.

Mikami, K.; Fustero, S.; Sánchez-Roselló, M.; Aceña, J. L.; Soloshonok, V. A.; Sorochinsky, A. E. (2011)
Synthesis of Fluorine Containing beta-Amino Acids
Synthesis

 
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